\(A/n_{Na_2SO_4}=0,1.2=0,2mol\\ n_{BaCl_2}=0,2.3=0,6mol\\ Na_2SO_4+BaCl_2\rightarrow BaSO_4+2NaCl\\ \Rightarrow\dfrac{0,2}{1}< \dfrac{0,6}{1}\Rightarrow BaCl_2.dư\\ Na_2SO_4+BaCl_2\rightarrow BaSO_4+2NaCl\)

0,2mol          0,2mol        0,2mol          0,4mol

\(m_{rắn}=m_{BaSO_4}=0,2.233=46,6g\\ B/C_{M_{NaCl}}=\dfrac{0,4}{0,1+0,2}=\dfrac{4}{3}M\\ C_{M_{BaCl_2}}=\dfrac{0,6-0,2}{0,1+0,2}=\dfrac{4}{3}M\)

\(n_{Na_2SO_4}=0,1.2=0,2\left(mol\right);n_{BaCl_2}=0,2.3=0,6\left(mol\right)\\ PTHH:Na_2SO_4+BaCl_2\rightarrow BaSO_4\downarrow+2NaCl\\ Vì:\dfrac{0,2}{1}< \dfrac{0,6}{1}\rightarrow BaCl_2dư\\ n_{BaSO_4}=n_{BaCl_2\left(p.ứ\right)}=n_{Na_2SO_4}=0,2\left(mol\right)\\ a,m_{rắn}=m_{BaSO_4}=233.0,2=46,6\left(g\right)\)

b, Dung dịch sau phản ứng có: NaCl và BaCl₂ dư

\(n_{BaCl_2\left(dư\right)}=0,6-0,2=0,4\left(mol\right)\\ n_{NaCl}=0,2.2=0,4\left(mol\right)\\V_{ddsau}=0,1+0,2=0,3\left(mol\right)\\ C_{MddBaCl_2}=\dfrac{0,4}{0,3}=\dfrac{4}{3}\left(M\right);C_{MddNaCl}=\dfrac{0,4}{0,3}=\dfrac{4}{3}\left(M\right)\)

a) BaCl₂ + Na₂SO₄ → BaSO₄↓ + 2NaCl

\(V_{ddBaCl_2}=\dfrac{240}{1,2}=200\left(ml\right)=0,2\left(l\right)\)

\(\Rightarrow n_{BaCl_2}=0,2\times1=0,2\left(mol\right)\)

\(m_{Na_2SO_4}=400\times14,2\%=56,8\left(g\right)\)

\(\Rightarrow n_{Na_2SO_4}=\dfrac{56,8}{142}=0,4\left(mol\right)\)

Theo PT: \(n_{BaCl_2}=n_{Na_2SO_4}\)

Theo bài: \(n_{BaCl_2}=\dfrac{1}{2}n_{Na_2SO_4}\)

Vì \(\dfrac{1}{2}< 1\) ⇒ BaCl₂ hết, Na₂SO₄ dư

b) Dung dịch A gồm: NaCl và Na₂SO₄ dư

Theo PT: \(n_{BaSO_4}=n_{BaCl_2}=0,2\left(mol\right)\)

\(\Rightarrow m_{BaSO_4}=0,2\times233=46,6\left(g\right)\)

\(\Rightarrow m_{dd}saupư=240+400-46,6=593,4\left(g\right)\)

Theo PT: \(n_{NaCl}=2n_{BaCl_2}=2\times0,2=0,4\left(mol\right)\)

\(\Rightarrow m_{NaCl}=0,4\times58,5=23,4\left(g\right)\)

\(\Rightarrow C\%_{NaCl}=\dfrac{23,4}{593,4}\times100\%=3,94\%\)

Theo PT: \(n_{Na_2SO_4}pư=n_{BaCl_2}=0,2\left(mol\right)\)

\(\Rightarrow n_{Na_2SO_4}dư=0,4-0,2=0,2\left(mol\right)\)

\(\Rightarrow m_{Na_2SO_4}dư=0,2\times142=28,4\left(g\right)\)

\(\Rightarrow C\%_{Na_2SO_4}dư=\dfrac{28,4}{593,4}\times100\%=4,79\%\)

\(n_{H_2SO_4}=1.0,2=0,2(mol)\\ H_2SO_4+BaCl_2\to BaSO_4\downarrow+2HCl\\ \Rightarrow n_{BaSO_4}=n_{BaCl_2}=0,2(mol)\\ a,m_{BaSO_4}=0,2.233=46,6(g)\\ b,V_{dd_{BaCl_2}}=\dfrac{0,2}{1,5}\approx 0,13(l)\\ c,n_{HCl}=0,4(mol)\\ \Rightarrow C_{M_{HCl}}=\dfrac{0,4}{0,2+0,13}\approx 1,21M\)

\(d,\) Dd sau p/ứ là HCl nên làm quỳ tím hóa đỏ

\(n_{H_2SO_4}=0,2.1=0,2\left(mol\right)\\ H_2SO_4+BaCl_2\rightarrow BaSO_4+2HCl\\ n_{BaCl_2}=n_{BaSO_4}=n_{H_2SO_4}=0,2\left(mol\right)\\ n_{HCl}=2.0,2=0,4\left(mol\right)\\ a,m_{\downarrow}=m_{BaSO_4}=0,2.233=46,6\left(g\right)\\ b,V_{\text{dd}BaCl_2}=\dfrac{0,2}{1,5}=\dfrac{2}{15}\left(l\right)\\ c,C_{M\text{dd}HCl}=\dfrac{0,4}{\dfrac{2}{15}+0,2}=1,2\left(M\right)\\ d,V\text{ì}.c\text{ó}.\text{dd}.HCl\Rightarrow Qu\text{ỳ}.ho\text{á}.\text{đ}\text{ỏ}\)

200ml = 0,2l

\(n_{H2SO4}=1.0,2=0,2\left(mol\right)\)

Pt : \(BaCl_2+H_2SO_4\rightarrow BaSO_4+2HCl|\)

           1           1                  1              2

          0,2        0,2               0,2           0,4

a) \(n_{BaSO4}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)

⇒ \(m_{BaSO4}=0,2.233=46,6\left(g\right)\)

b) \(n_{BaCl2}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)

\(V_{ddBaCl2}=\dfrac{0,2}{1,5}=\dfrac{2}{15}\left(l\right)=133,33\left(ml\right)\)

c) \(n_{HCl}=\dfrac{0,2.2}{1}=0,4\left(mol\right)\)

\(V_{ddspu}=0,2+\dfrac{2}{15}=\dfrac{1}{3}\left(l\right)\)

\(C_{M_{ddHCl}}=\dfrac{0,4}{\dfrac{1}{3}}=1,2\left(M\right)\)

d) Cho quỳ tím vào dung dịch sau phản ứng , quỳ tím hóa đỏ. Vì dung dịch thu được sau phản ứng có HCl là axit

 Chúc bạn học tốt

a)

$K_2SO_4 + BaCl_2 \to BaSO_4 + 2KCl$

b)

$n_{K_2SO_4} = 0,2.2 = 0,4(mol)$
$n_{BaCl_2} = 0,3.1 = 0,3(mol)$

Ta thấy : 

$n_{K_2SO_4} : 1 > n_{BaCl_2} : 1$ nên $K_2SO_4$ dư

$n_{BaSO_4} = n_{BaCl_2} = 0,3(mol)$
$m_{BaSO_4} = 0,3.233 = 69,9(gam)$

c) $n_{K_2SO_4} = 0,4 - 0,3 = 0,1(mol)$

$V_{dd\ sau\ pư} = 0,2 + 0,3 = 0,5(lít)$

$C_{M_{K_2SO_4} } = \dfrac{0,1}{0,5} = 0,2M$
$C_{M_{KCl}} = \dfrac{0,6}{0,5} = 1,2M$

\(n_{BaCl_2}=\dfrac{150.16,64\%}{137+35.2}=0,12\left(mol\right)\)

\(n_{H_2SO_4}=\dfrac{100.14,7\%}{98}=0,15\left(mol\right)\)

Phương trình hóa học : 

BaCl₂ + H₂SO₄ -----> BaSO₄ + 2HCl 

Dễ thấy \(\dfrac{n_{BaCl_2}}{1}< \dfrac{n_{H_2SO_4}}{1}\Rightarrow H_2SO_4\text{ dư }0,15-0,12=0,03\left(mol\right)\)

c) Khối lượng kết tủa : 

\(m_{BaSO_4}=0,12.233=27,96\) (g) 

Khối lượng chất tan : \(m_{HCl}=0,24.36,5=8,76\left(g\right)\) ; 

\(m_{H_2SO_4\left(\text{dư}\right)}=0,03.98=2,94\left(g\right)\) 

c) \(C\%_{H_2SO_4}\)= \(\dfrac{2,94}{150+100}.100\%=1,176\%\)

_{\(C\%_{HCl}=\dfrac{8,76}{150+100}.100\%=3.504\%\)}

d) NaOH + HCl ---> NaCl + H₂O 

      0,24 <-- 0,24

       mol       mol

    2NaOH + H₂SO₄  ---> Na₂SO₄ + 2H₂O

  0,06 mol <-- 0,03 mol  

\(\Rightarrow n_{NaOH}=0,24+0,06=0,3\left(mol\right)\)

\(V_{NaOH}=0,3.2=0,6\left(l\right)\)

a. PTHH    BaCl2 + H2SO4 → BaSO4↓ + 2HCl

b. _ mBaCl2 = 16,61.150:100 = 24,96 g

nBaCl2 = 24.96:208 = 0,12 mol

_ mH2SO4 = 14,7.100:100 = 14,7 g

nH2SO4 = 14,7:98 = 0,15 mol

Ta thấy: nBaCl2 < nH2SO4 ⇒ BaCl2 hết, H2SO4 dư

a) \(NaOH+HCl\rightarrow NaCl+H_2O\)

0,1................0,3

LẬp tỉ lệ : \(\dfrac{0,1}{1}< \dfrac{0,3}{1}\)=> Sau pứ HCl dư

\(m_{NaCl}=0,1.58,5=5,85\left(g\right)\)

b) \(CM_{NaCl}=\dfrac{0,1}{0,2+0,3}=0,2M\)

\(CM_{HCl\left(dư\right)}=\dfrac{\left(0,3-0,1\right)}{0,2+0,3}=0,4M\)

a) \(n_{CH_3COOH}=\dfrac{120.20\%}{60}=0,4\left(mol\right)\)

\(n_{Na_2CO_3}=\dfrac{53.30\%}{106}=0,15\left(mol\right)\)

PTHH: Na₂CO₃ + 2CH₃COOH --> 2CH₃COONa + CO₂ + H₂O

Xét tỉ lệ: \(\dfrac{0,15}{1}< \dfrac{0,4}{2}\) => Na₂CO₃ hết, CH₃COOH dư

PTHH: Na₂CO₃ + 2CH₃COOH --> 2CH₃COONa + CO₂ + H₂O

                0,15-------->0,3-------------->0,3------->0,15

=> \(m_{CH_3COONa}=0,3.82=24,6\left(g\right)\)

b) m_{dd sau pư} = 120 + 53 - 0,15.44 = 166,4 (g)

=> \(C\%=\dfrac{24,6}{166,4}.100\%=14,78\text{%}\)